New Nickel and Copper Complexes With Thiacalix[4]Arene Derivative Synthesis, Characterization and Catalytic Activity
DOI:
https://doi.org/10.47134/pslse.v2i2.336Keywords:
Ring Opening Polymerization, thiacalix[4]arene, Bromopropyl, Ni(II) and Cu(II)Abstract
The study investigates the synthesis and characterization of p-tert-butylthiacalix[4]arene derivative via interaction between p-tert-butylthiacalix[4]arene with two equivalent of 1-bromopropyl to form di-substituted thiacalix[4]arene ring. It is employed to prepare complexes with Ni(II) and Cu(II). The ligand and it is complexes were characterized using elemental analysis, infrared and proton nuclear resonance. Polymerization of cyclic esters was assisted via prepared complexes. The result shows capability of these compounds as catalyst for such reaction.
References
Al-Khafaji, Y.F., et al., Ring opening polymerization of lactides and lactones by multimetallic alkyl zinc complexes derived from the acids Ph2C(X)CO2H (X = OH, NH2). RSC Advances, 2017. 7(8): p. 4510-4517.
Al‐Khafaji, Y.F., et al., Multimetallic lithium complexes derived from the acids Ph2C (X) CO2H (X= OH, NH2): synthesis, structure and ring opening polymerization of lactides and lactones. ChemistrySelect, 2017. 2(2): p. 759-768. DOI: https://doi.org/10.1002/slct.201602029
Al-Khafaji, Y.F., et al., Ring opening polymerization of lactides and lactones by multimetallic alkyl zinc complexes derived from the acids Ph 2 C (X) CO 2 H (X= OH, NH 2). RSC advances, 2017. 7(8): p. 4510-4517. DOI: https://doi.org/10.1039/C6RA26746G
AL-KHAFAJI, Y.F., et al., Synthesis and characterization of niobium and tantalum complexes with bidentate ligand and its use in ring opening polymerization of ε-caprolactone. Asian Journal of Chemistry, 2018. 30(2): p. 460-462. DOI: https://doi.org/10.14233/ajchem.2018.21144
Angell, S.E., et al., Hemilabile coordination complexes for sensing applications. Coordination chemistry reviews, 2006. 250(13-14): p. 1829-1841. DOI: https://doi.org/10.1016/j.ccr.2006.03.023
Al-khafaji, Y.F., S.M. H.Obai, and A.O. Husseinc, Ring Opining polymerization of caprolactone And Antibacterial activity by Mixed Ligand of Metal(II) and (III) Complexes. Egyptian Journal of Chemistry, 2023. 66(6): p. 85-93.
Atta, S., et al., Ring opening polymerization of ε-caprolactone through water. Polymer Chemistry, 2021. 12(2): p. 159-164. DOI: https://doi.org/10.1039/D0PY01481H
Benesperi, I., R. Singh, and M. Freitag, Copper Coordination Complexes for Energy-Relevant Applications. Energies, 2020. 13(9): p. 2198. DOI: https://doi.org/10.3390/en13092198
Chopparapu, R., et al. A review article on water purification techniques by using fiber composites and biodegradable polymers. in AIP Conference Proceedings. 2020. AIP Publishing. DOI: https://doi.org/10.1063/5.0004069
Daniel, S., Biodegradable polymeric materials for medicinal applications. Green Composites, 2021: p. 351-372. DOI: https://doi.org/10.1007/978-981-15-9643-8_13
Fisher, J., R. Potter, and C. Barnard, Applications of coordination complexes. Platinum Metals Review, 2004. 48(3): p. 101-104. DOI: https://doi.org/10.1595/147106704X1621
Ge, F., et al., Vanadium(v) phenolate complexes for ring opening homo- and co-polymerisation of ε-caprolactone, l-lactide and rac-lactide. RSC Advances, 2016. 6(6): p. 4792-4802. DOI: https://doi.org/10.1039/C5RA24816G
Hussein, F.H. and Y.F. Al-Khafaji, 4 - Biopolymers, biocomposites, and their types, in Advanced Green Materials, S. Ahmed, Editor. 2021, Woodhead Publishing. p. 43-60. DOI: https://doi.org/10.1016/B978-0-12-819988-6.00004-5
Ismail, A. and Y. Al-Khafaji, Preparation And Characterization Of Calixarene Derivative Complexes And Their Application As Catalysis For Ring Opening Polymerization Of e-Caprolactone. Egyptian Journal of Chemistry, 2020. 63(12): p. 4911-4916. DOI: https://doi.org/10.21608/ejchem.2020.30944.2660
Kiselev, E., N. Zhila, and T. Volova. Biodegradable polymers–perspectives and applications in agriculture. in IOP Conference Series: Earth and Environmental Science. 2021. IOP Publishing. DOI: https://doi.org/10.1088/1755-1315/689/1/012036
Kim, K., et al., Thiacalix [4] arene-Based Three-Dimensional Coordination Polymers Incorporating Neutral Bridging Coligands. Crystal growth & design, 2011. 11(9): p. 4059-4067. DOI: https://doi.org/10.1021/cg2006315
Malinowski, J., et al., Application of coordination compounds with transition metal ions in the chemical industry—A review. International Journal of Molecular Sciences, 2020. 21(15): p. 5443. DOI: https://doi.org/10.3390/ijms21155443
Makarov, E., et al., Synthesis of functional (thia) calix [4] arene derivatives using modular azide-alkyne cycloaddition approach. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2023. 103(9): p. 319-353. DOI: https://doi.org/10.1007/s10847-023-01200-6
Makarov, E., et al., Correction: Synthesis of functional (thia) calix [4] arene derivatives using modular azide-alkyne cycloaddition approach. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2023. 103(9): p. 355-368. DOI: https://doi.org/10.1007/s10847-023-01202-4
Maraveas, C., Production of sustainable and biodegradable polymers from agricultural waste. Polymers, 2020. 12(5): p. 1127. DOI: https://doi.org/10.3390/polym12051127
Naumann, S., et al., Dual catalysis for selective ring-opening polymerization of lactones: Evolution toward simplicity. Journal of the American Chemical Society, 2015. 137(45): p. 14439-14445. DOI: https://doi.org/10.1021/jacs.5b09502
Samir, A., et al., Recent advances in biodegradable polymers for sustainable applications. Npj Materials Degradation, 2022. 6(1): p. 68. DOI: https://doi.org/10.1038/s41529-022-00277-7
Shurpik, D.N., et al., Hybrid multicyclophanes based on thiacalix [4] arene and pillar [5] arene: Synthesis and influence on the formation of polyaniline. Organic Chemistry Frontiers, 2018. 5(19): p. 2780-2786. DOI: https://doi.org/10.1039/C8QO00652K
Ulery, B.D., L.S. Nair, and C.T. Laurencin, Biomedical applications of biodegradable polymers. Journal of polymer science Part B: polymer physics, 2011. 49(12): p. 832-864. DOI: https://doi.org/10.1002/polb.22259
von Schenck, H., et al., Ring-opening polymerization of lactones and lactides with Sn (IV) and Al (III) initiators. Macromolecules, 2002. 35(5): p. 1556-1562. DOI: https://doi.org/10.1021/ma011653i
Xiong, K., et al., Self-assembly of thiacalix [4] arene-supported nickel (II)/cobalt (II) complexes sustained by in situ generated 5-methyltetrazolate ligand. Crystal growth & design, 2012. 12(6): p. 3335-3341. DOI: https://doi.org/10.1021/cg300483c
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